Jiangsu Tetra New Material Technology Co., Ltd.
Jiangsu Tetra New Material Technology Co., Ltd.

Epoxy Resin TTA26 — A New-Generation Material for Cationic Flexible Packaging Inks

Table of Content [Hide]

    Flexible packaging is widely used in the food industry. With the growing emphasis on food safety, increasingly stringent requirements are being placed on inks used for food packaging. Although traditional UV acrylate free-radical curing inks offer fast curing speeds, they still have shortcomings in terms of migration, resistance to retort processing, adhesion, and flexibility. UV cationic systems, however, can effectively overcome these limitations of free-radical systems. The key lies in the use of a flexible cycloaliphatic epoxy resin—TTA26—as the main resin.



    Epoxy_Resin_TTA26.png



    Tetra Epoxy Resin TTA26 is a typical cycloaliphatic difunctional epoxy resin. It is well known for its “excellent flexibility and cured film performance,” making it particularly suitable for cationic curing systems with high flexibility requirements. Its key application performance advantages are as follows:



    01 Excellent flexibility

    The introduction of an adipate ester bridge chain into the TTA26 molecular structure imparts outstanding flexibility and crack resistance to the ink film.



    02 Low migration

    The difunctionality of TTA26 provides good cationic curing activity, enabling rapid and complete curing in inks and resulting in low migration.



    03 Good adhesion after curing

    Epoxy resins exhibit low curing shrinkage, leading to strong adhesion between the ink film and flexible substrates.




    Recommended applications

    Food flexible packaging printing inks and overprint varnishes.


    Food_flexible_packaging_printing_inks_and_overprint_varnishes..png


    Reference formulation


    Component

    Parts by weight

    Function

    TTA26

    35–60

    Main resin, provides flexibility and adhesion

    Reactive diluent

    10–20

    Viscosity reduction, film thickness control

    Photoinitiator

    2–5

    Initiates cationic polymerization

    Pigment paste

    20–30

    Provides color

    Additives

    0.5–2

    Improves printability and stability



    Test results:


    To meet the stringent requirements of food packaging, Tetra Epoxy Resin TTA26 was systematically evaluated from four aspects: food safety, mechanical properties, heat and water resistance, and chemical/media resistance. Test data confirm that its overall performance fully complies with the strict standards for food packaging inks. It not only effectively eliminates migration risks at the source, but also ensures excellent physical and chemical stability of the packaging during processing, transportation, and storage—providing brand owners with a reliable “technical assurance.”




    No.

    Category

    Test Item

    Reference Standard

    Acceptance Criteria

    Main Standard

    Cationic System Result

    Free-Radical System Result

    1

    Food safety

    Overall migration

    EU 10/2011

    ≤ 10 mg/dm²

    EU 10/2011

    2

    Curing & mechanical performance

    Degree of UV curing

    ISO 15742

    Fully cured, no tack or transfer

    ISO 15742

    Adhesion (initial)

    ISO 2409

    ≤ Class 1

    ISO 2409

    Scratch resistance

    ISO 1518

    No visible scratches

    ISO 1518

    Flexibility

    ISO 1519

    No cracks, no delamination

    ISO 1519

    Tensile compatibility

    ISO 527(ref.)

    No cracking or delamination

    ISO 527(ref.)

    3

    Heat & water resistance

    Boiling water resistance

    ISO 2812-2

    No blistering, no peeling, adhesion ≤ Class 1

    ISO 2812-2

    Damp heat aging

    ISO 6270-2

    No blistering, no discoloration

    ISO 6270-2

    4

    Chemical & media resistance

    Grease resistance

    ISO 2812-1

    No obvious discoloration or peeling

    ISO 2812-1

    Alcohol rub resistance

    ISO 2836

    No fading or peeling

    ISO 2836




    Conclusion

    With its unique alicyclic structure and cationic curing characteristics, TTA26 successfully addresses the long-standing challenge in flexible packaging inks of balancing toughness and retort resistance. It not only enhances the adhesion and stability of printed layers, but also offers new directions for green, high-performance ink formulations. In the future wave of environmentally friendly and high-performance packaging materials, TTA26 is more than just a resin—it is a key material driving the advancement of flexible printing technology.



    References